Search results for "effect [strong interaction]"
showing 10 items of 170 documents
Modelling of microcracked bodies using the concept of crack opening mode
2010
Effect of temperature on soil microbial structure and fractionation during C mineralisation
2008
International audience; Microbial carbon mineralization in soils leads to the production of different gaseous or dissolved components that have environmental impacts. Our study deals with the influence of soil temperature on the production of gaseous and dissolved carbon components during carbon mineralization in forest soils in France. After an incubation of soil samples for 42 days at 4 different temperatures, we determined both size and 13C isotopic signature of dissolved organic carbon and CO2 pools. We also characterised the soil microbial community structure (PLFA profiles). While temperature clearly increases the CO2 production, a low decrease of the dissolved organic carbon pool was…
Electroactive Liquid Crystalline Polymers ☆
2017
As with low molecular mass liquid crystals, the polymeric liquid crystalline compounds show many possibilities for interaction with electrical fields. Charge transport via the aromatic cores allows the construction of light emitting devices, field effect transistors and photovoltaic cells. The order of the liquid crystalline phases helps to improve intramolecular charge transfer and the mobility allows easy alignment. Liquid crystalline polymers with ferroelectric phases can be used in fast switching optical devices. Their unique switching mechanism proceeds under reduced interaction with the polymer chains. The combination of liquid crystallinity with elastomer networks leads to electromec…
On the relations between aromaticity and substituent effect
2019
Aromaticity/aromatic and substituent/substituent effects belong to the most commonly used terms in organic chemistry and related fields. The quantitative description of aromaticity is based on energetic, geometric (e.g., HOMA), magnetic (e.g., NICS) and reactivity criteria, as well as the properties of the electronic structure (e.g., FLU). The substituent effect can be described using either traditional Hammett-type substituent constants or characteristics based on quantum-chemistry. For this purpose, the energies of properly designed homodesmotic reactions and electron density distribution are used. In the first case, a descriptor named SESE (energy stabilizing the substituent effect) is o…
Organic Field Effect Transistors: Noncovalent Functionalization and Passivation of Black Phosphorus with Optimized Perylene Diimides for Hybrid Field…
2020
Creatividad Organizacional: un estudio cuantitativo de la eficacia de los programas de entrenamiento en creatividad
2016
Las organizaciones actuales necesitan desarrollar sus mejores capacidades para sobrevivir en entornos altamente dinámicos y exigentes, para ello la creatividad resulta esencial. Con el objetivo de potenciar la creatividad en las organizaciones se han desarrollado numerosos programas de entrenamiento, pero muy pocos se han sometido a un análisis científico que avale su eficacia. Los escasos datos existentes sobre la eficacia son, frecuentemente, contradictorios, lo que indica la necesidad de abordar un estudio de concreción de tales resultados. La presente investigación analiza y sintetiza los resultados obtenidos en 32 estudios primarios sobre la eficacia de los programas de entrenamiento d…
Dielectrophoresis as an assembly method for carbon nanotube memory elements
2010
The experiments described in this Master's thesis aim to assess the practicality of using dielectrophoresis (DEP) for assembling memory elements from carbon nanotubes (CNTs). These elements were field-effect transistors (FETs) with a wide hysteresis window. The devices assessed were made on a silicon substrate with a HfO2 - TiO2 - HfO2 gate dielectric layer to ensure a predictable hysteresis for memory operation. The FETs were used for further research in regard to environmental effects in their operation. An average yield of 12.5 % over 26 different trapping attempts, a total of 650 gaps, was achieved for single trapped CNTs in a two-electrode configuration with a 1 µm gap between electrod…
Substituent effects of nitro group in cyclic compounds
2020
AbstractNumerous studies on nitro group properties are associated with its high electron-withdrawing ability, by means of both resonance and inductive effect. The substituent effect of the nitro group may be well described using either traditional substituent constants or characteristics based on quantum chemistry, i.e., cSAR, SESE, and pEDA/sEDA models. Interestingly, the cSAR descriptor allows to describe the electron-attracting properties of the nitro group regardless of the position and the type of system. Analysis of classical and reverse substituent effects of the nitro group in various systems indicates strong pi-electron interactions with electron-donating substituents due to the re…
effect of the temperature on the electrochemical incineration of organic pollutants
2009
Aligned microcontact printing of biomolecules on microelectronic device surfaces
2001
Microcontact printing (/spl mu/CP) of extracellular matrix proteins is a fascinating approach to control cell positioning and outgrowth, which is essential in the development of applications ranging from cellular biosensors to tissue engineering. Microelectronic devices can be used to detect the activity from a large number of recording sites over the long term. However, signals from cells can only be recorded at small sensitive spots. Here, the authors present an innovative setup to perform aligned /spl mu/CP of extracellular matrix proteins on microelectronic devices in order to guide the growth of electrogenic cells specifically to these sensitive spots. The authors' system is based on t…